Rhodamine B Photodegradation Using Silver Phosphate-Hydroxyapatite Composites From Skipjack Tuna Bones (Katsuwonus pelamis)
DOI:
https://doi.org/10.35799/jis.v23i2.50469Keywords:
Ag3PO4, photodegradation, hydroxyapatite, rhodamine B, skipjack tuna boneAbstract
Hydroxyapatite (HAp) treated with silver would produce silver phosphate (Ag3PO4), which is a semiconducting material and can degrade synthetic dyes. This study aimed to synthesize a composite material with the main components of HAp from skipjack (Katsuwonus pelamis) bone and Ag3PO4 used to degrade the synthetic dye Rhodamin B (RB) in aqueous solution. The resulting material was characterized using X-Ray Diffraction (XRD), Scanning Electron Microscopy with Energy-Dispersive X-Ray (SEM-EDX), and Fourier Transform Infrared (FTIR) Spectroscopy. The photodegradation of Rhodamine B was evaluated under visible light irradiation with variations in the number of composites, irradiation intensity, and irradiation time. Characterization results showed the formation of Ag3PO4/HAp composites, and photodegradation tests showed that the higher the amount of photocatalyst used and the higher the light intensity, the more synthetic dyes were degraded.
Keywords: Ag3PO4; photodegradation; hydroxyapatite; rhodamine B; skipjack tuna bone
References
Fauzi, W.A., Simpen, I.N., & Sudiarta I.W. (2019). Sintesis dan Karakterisasi Zeolite-TiO2 Serta Pemanfaatannya Sebagai Fotokatalis Untuk Degradasi Rhodamin B. Jurnal Kimia (Journal of Chemistry), 13(1), 74–81.
Joshi, K.M., & Shrivastava, V. (2010). Removal of hazardious textile dyes from aqueous solution by using commercial activated carbon with TiO2 and ZnO as photocatalyst. International Journal of ChemTech Research, 2(1), 427–435.
Khan, A., Qamar, M., & Muneer, M. (2012). Synthesis of highly active visible-light-driven colloidal silver orthophosphate. Chemical Physics Letters, 519–520, 54–58. https://doi.org/https://doi.org/10.1016/j.cplett.2011.11.015
Liu, W., Wang, M., Xu, C., Chen, S., & Fu, X. (2013). Ag3PO4/ZnO: An efficient visible-light-sensitized composite with its application in photocatalytic degradation of Rhodamine B. Materials Research Bulletin, 48(1), 106–113.
Luo, L., Li, Y., Hou, J., & Yang, Y. (2014). Visible photocatalysis and photostability of Ag3PO4 photocatalyst. Applied Surface Science, 319, 332–338. https://doi.org/https://doi.org/10.1016/j.apsusc.2014.04.154
Ma, J., Zou, J., Li, L., Yao, C., Zhang, T., & Li, D. (2013). Synthesis and characterization of Ag3PO4 immobilized in bentonite for the sunlight-driven degradation of Orange II. Applied Catalysis B: Environmental, 134–135, 1–6. https://doi.org/https://doi.org/10.1016/j.apcatb.2012.12.032
Morgan, H., Wilson, R.M., Elliott, J.C., Dowker, S.E.P., & Anderson, P. (2000). Preparation and characterisation of monoclinic hydroxyapatite and its precipitated carbonate apatite intermediate. Biomaterials, 21(6), 617–627. https://doi.org/https://doi.org/10.1016/S0142-9612(99)00225-2
Muarip, S., Artsanti, P., Fajriati, I., & Krisdiyanto, D. (2020). Fotodegradasi Zat Warna Rhodamin B Dengan Fotokatalis Komposit TiO2-SiO2. Indonesian Journal of Materials Chemistry, 3(1), 15–18.
Mutmainnah, Chadijah, S., & Rustiah, W.O. (2017). Hidroksiapatit dari Tulang Ikan Tuna Sirip Kuning (Tunnus albacores) dengan Metode Presipitasi. Al-Kimia, 5(2), 119–126.
Pangajow, S.E.M., Wuntu, A., & Sangi, M.S. (2019). Kinetika Fotodegradsi Methylene Blue Menggunakan Komposit Ag3PO4/Ag/HAp Tilang Ikan Kakap Merah (Lutjanus sp.). Chemistry Progress, 12(2), 93–95.
Pattanayak, D. K., Divya, P., Upadhyay, S., Prasad, R. C., Rao, B. T., & Mohan, T. R. R. (2005). Synthesis and Evaluation of Hydroxyapatite Ceramics. Trends in Biomaterials & Artificial Organs, 18(2), 87–92.
Piccirillo, C., Pinto, R. A., Tobaldi, D. M., Pullar, R. C., Labrincha, J. A., Pintado, M. M. E., & Castro, P. M. L. (2015). Light induced antibacterial activity and photocatalytic properties of Ag/Ag3PO4 -based material of marine origin. Journal of Photochemistry and Photobiology A: Chemistry, 296, 40–47. https://doi.org/https://doi.org/10.1016/j.jphotochem.2014.09.012
Priya, P. G., Ramamurthi, V., & Anand, P. (2011). Degradation Studies of Tannery Effluents using Electro Flotation Technique. Journal of Chemical Engineering & Process Technology, 2(1), 104-107. Doi:10.4172/2157-7048.1000104
Widjajanti, E., Tutik, R., & Utomo, M.P. (2011). Pola Adsorpsi Zeolit Terhadap Pewarna Azo Metil Merah Dan Metil Jingga. Prosiding Seminar Nasional Penelitian, Pendidikan Dan Penerapan MIPA.
Zheng, B., Wang, X., Liu, C., Tan, K., Xie, Z., & Zheng, L. (2013). High-Efficiently Visible Light-Responsive Photocatalysts:Ag3PO4 Tetrahedral Microcrystals With Exposed {111} Facets of High Surface Energy. Journal of Materials Chemistry A, 1, 12635–12640.
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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License